No it will not... ( 500F )
average heated rotors are around 800 to 1000F
spirited driving can send the rotors to 1200/1500F.
All out road racing can get the rotors glowing @1800 + F
You can buy header paint @1500 F from a speed shop
or you can buy VHT ( Very High Temp. ) 1200F from places like Pep Boys, Auto Zone, or Advanced auto..