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I had this happen with a Holley spreadbore on mine some years ago. The carb was a used/rebuilt unit, I never could get it to stop. Best I could surmise it was literally siphoning gas from the tank and the needles and seats weren't closing well enough to stop it. It had non-externally adjustable floats so I had to keep pulling the bowls to try and float-adjust it out, after several tries I just gave up and put the (semi-) trusty old QJet back on. Never did get to the bottom of it and I haven't yet seen a conclusive thread post on this greatest of all car forums to get to the bottom of exactly what was causing it...grrrr.
Fuel percolation. I installed a Holley Street Dominator intake, 3310 carb. with Holley chrome air cleaner on my '77 L82 back in the day. Was in the summer time in Dallas. Pulled in to stop and same thing as yours happened. The heat from the Vette engine compartment, Dallas summer, aluminum intake, non blocked heat cross over and running it hard led to boiling the fuel. I ran the same exact setup on my '74 Z28 and never had this happen. I blocked the heat crossover at the intake gasket with the little metal plates, Mr. Gasket and installed an insulator under the carb. where you have a gasket, aluminum plate, gasket, aluminum plate, gasket, with about six layers. I never got it to completely stop on those 105 degree days but it did much better. I think this is what you are seeing. Good luck with it, mike.
I would like to know if anyone else knows if this will occur with a Q-jet on an aluminum intake with the crossover not blocked. I still have the polished
Holley intake.
I had a similar problem with a vented cap that vented to wrong way for my car(68). It would vent in as fuel was used but would not vent out when stopped and heat built up. This would push fuel into the engine. Be sure you a the correct vented direction cap!