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electrolysis rust removal question

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Old Aug 29, 2011 | 05:26 AM
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Default electrolysis rust removal question

For those who have used this, what does the metal look like after the rust is removed?

The reason why I ask is that I have seen videos where the metal from the part which had the rust removed was black afterwards, and another where it was regular gray/silver metal color.
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Old Aug 29, 2011 | 07:37 AM
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I've experimented a little and everything has been black so far. Most have said the black can be removed.

Dupont sells a can of spray rust restore that says it leaves a black paint-able coating of black oxide. I wonder if whats left from the electrolysis process is the same as the Dupont spray (which is acid) ?
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Old Aug 29, 2011 | 09:55 AM
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a little off the topic. i've used the rust removal chemicals(not acids) on small items. the name "rust doctor" comes to mind. the stuff works very well and won't damage plastic or rubber. i think harbor freight sells something like it.
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Old Aug 29, 2011 | 10:29 AM
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Harbor Freight sells Evaoprust and it works well. I was surprised the first time I saw it work. I used them on my seat latch parts. After a day they came out pure and silver:

Before:


After:




Evaoprust leaves a coating that can be rinsed off with soap and water. I would dry my parts immediately with pressureized air and then prime/paint.

I love that stuff. What is simpler than dunking a part and then rising?
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Old Aug 29, 2011 | 10:51 PM
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Right out of the bucket, it'll have a black film on it. The film easily rinses off with some water and a scub brush leaving the bare metal.

And Evap-o-rust works great too, it's one of my favorite products

Last edited by Bugman Jeff; Aug 29, 2011 at 10:53 PM.
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Old Aug 29, 2011 | 11:24 PM
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Originally Posted by ...Roger...
Dupont sells a can of spray rust restore that says it leaves a black paint-able coating of black oxide. I wonder if whats left from the electrolysis process is the same as the Dupont spray (which is acid) ?
I don't think so. The black left by the spray on stuff is Iron Phosphate fromed from the reaction between the iron and the phosphoric acid in the conversion coating. I used to know what the black coating electrolysis is, but it's since slipped my mind. I want to say it's also iron phosphate, but I don't know where the phosphorus for the reaction would come from.
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Old Aug 30, 2011 | 01:43 AM
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Almost all those products contain phosphoric acld and ethyline glycol, to varying concentrations, including Evaporust.
The Dupont 5717s and 225s have lower concentrations as well.
Dupont 226s has hydroflouric acid and worst well for aluminum.

Evaporust just has such lower concentrations that it doesn't have to qualify it as an acid. Also why it takes longer.

If you rinse any of them off when wet, you will have bare metal.
If you let the black coating dry on, it becomes the phosphate protective costing. AKA cold black oxide.
Black Oxide is the better process using hot a alkaline salt solution usually for bolts etc.

In all cases, if you remove the black coating, you have removed the rust protectant.
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Old Aug 30, 2011 | 10:02 AM
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Originally Posted by JLinNY
For those who have used this, what does the metal look like after the rust is removed?

The reason why I ask is that I have seen videos where the metal from the part which had the rust removed was black afterwards, and another where it was regular gray/silver metal color.
I'm not sure what its called.. but the black left on the part, well we call it ****. It cleans off with a wet rag. At least it does in ours.

You can make your own tank with a 55 gallon plastic drum, battery charger, copper coated ground rods and anodes.... toss in some sodium hydroxide as a cleaner and sodium carbonate for an electrolyte... and your all set!

Last edited by Willcox Corvette; Aug 30, 2011 at 10:06 AM.
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