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All great stuff so far. Max HP will be a result of your tune. I have seen some get 30rwhp with tune and some a little over 40rwhp. As mentioned, Kooks, ARH, LG's all produce pretty similar gains as well as some of the budget brands. If $$ were no object for me I would look really hard at the LG Pros and get them coated. However, for that last couple of hp they would provide I would have over $1k left over (using XS Power) that I can easily get a cam with or do something else. Do you plan on other mods?
+1 for LG Pros, but Kooks and ARH also have a quality product. To coat them or not is another subject of intense debate. I didn't and have no issues. You can install the LG x-pipe and hi-flow cats, maintain the O2 sensors and stay emissions compliant (if that's important) and still pick up over 30HP with stock Ti exhaust.
Good luck.
In addition to our high qualtiy cat back exhaust, Billy Boat Exhaust also makes a great CARB legal 4/2/1 C5 shorty header. 50 state leagal, yes even California, NY and Ohio.
Also, race engineered long tubes w/ high flow cats for the C5, C6, Z06 and ZR-1's. Check them out at www.bbexhaust.com.
The answer to your question lies in where you want to end up. If you think you'll end up with a wild head/cam setup or a supercharger then go with LG Pros or one of the other premium long tube headers like ARH. On the other hand, if you think you're likely to end up with 500 RWHP or less then it's really hard to be LG Streets w/high flow cats and x-pipe. The factory Ti catback works great with this combination. You'll save anywhere from $500-$800 on a premium long tube setup, and you'll be thrilled with the results. Like someone else said, a good dyno tune is essential. Good luck with whatever you decide.