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Yesterday our 2001 started doing something new. The A/C will only work sometimes. About half the time you try to turn it on, the A/C light will light and then go out. The A/C will then blow warm air. If you shut the car off and restart it, the A/C may work perfect. Then, it may or may not work on the next start up. I originally thought about a bad ground, but the odd part is, once it's on, it won't go off by itself until the key is cycled.
I would pull the codes through the DIC to see if there might be an actuator issue, but most likely it is a little low on Freon. That will make the a/c light flash and go off.
OK... No HVAC codes in the system. When the A/C stays on, it will get cold enough to chase you out of the car.
You'll have to trust me on this. Or you could go to Google and search "C5 a/c won't stay on" and read the many cases where it fixed it. Low Freon can cause it. Does your outside air temp read correctly?