oil viscosity
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A genuine explanation of PAO versus Fischer-Tropsch is beyond the scope of this post, but one sentence descriptions follow. In the PAO route, you start with ethylene, polymerize that to make alpha olefins, use a different catalyst to polymerize the alpha olefins into PAO’s, then hydrotreat the PAO’s to make the finished long chain isoparaffins. In Fischer-Tropsch, you gasify natural gas into syngas (carbon monoxide plus hydrogen), then use the Fischer-Tropsch reaction to generate long chain paraffins which don’t have much chain branching, then isomerize the Fischer-Tropsch product into the finished long chain isoparaffins.
One could debate the small quality differences between PAO and Fischer-Tropsch isoparaffins, but both are clearly at least a bit better as lube base stocks than the hydrocracked dino oil synthetics due to absence of naphthenes. However, the Shell/Pennzoil base oil is pure Fischer-Tropsch, where as far as I know, there are no longer any pure PAO’s on the market (all are blends of PAO and hydrocracked dino oil which because of the hydrocracked dino oil, have small amounts of naphthenes). That said, motor oil is a mix of base oil and additives, so since the disadvantage of the hydrocracked dino oil is very small, one can certainly not conclude that the Shell/Pennzoil lubes are best of the best. A better additive package could easily overcome the very small disadvantage of a few naphthenes coming from the hydrocracked dino oil in the others.
Mobil 1 was never ester-based. In the early years it was pure PAO (poly alpha olefin). Since the BP/Castrol lawsuit in the late 1990’s, severely hydrocracked dino oil was allowed to be called a full synthetic. Since it is much cheaper to make, almost all full synthetics (including Mobil 1) are now blends of PAO and hydrocracked dino oil. The only exceptions I know of are the few ester-based oils like Redline and Motul, and Shell’s natural gas-based synthetic marketed mostly as Pennzoil Platinum.
As others have said, why make a change from what has allowed the car to go 100,000+ miles? I’d stick with the 5W30 full synthetic of the brand of your choosing (but would not go ester-based unless I was convinced the gasket/seal issue had been solved).
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Mobil 1 was never ester-based. In the early years it was pure PAO (poly alpha olefin). Since the BP/Castrol lawsuit in the late 1990’s, severely hydrocracked dino oil was allowed to be called a full synthetic. Since it is much cheaper to make, almost all full synthetics (including Mobil 1) are now blends of PAO and hydrocracked dino oil. The only exceptions I know of are the few ester-based oils like Redline and Motul, and Shell’s natural gas-based synthetic marketed mostly as Pennzoil Platinum.
As others have said, why make a change from what has allowed the car to go 100,000+ miles? I’d stick with the 5W30 full synthetic of the brand of your choosing (but would not go ester-based unless I was convinced the gasket/seal issue had been solved).
About seal/gasket i have to say that every old "from tube paste seal" (more than 15 years in use) have been destroyed by ester based oils. No problem however with any after 2005 factory crafted gasket or recently applied pastes.
Last edited by Blackship; Aug 13, 2023 at 07:45 AM.
A genuine explanation of PAO versus Fischer-Tropsch is beyond the scope of this post, but one sentence descriptions follow. In the PAO route, you start with ethylene, polymerize that to make alpha olefins, use a different catalyst to polymerize the alpha olefins into PAO’s, then hydrotreat the PAO’s to make the finished long chain isoparaffins. In Fischer-Tropsch, you gasify natural gas into syngas (carbon monoxide plus hydrogen), then use the Fischer-Tropsch reaction to generate long chain paraffins which don’t have much chain branching, then isomerize the Fischer-Tropsch product into the finished long chain isoparaffins.
One could debate the small quality differences between PAO and Fischer-Tropsch isoparaffins, but both are clearly at least a bit better as lube base stocks than the hydrocracked dino oil synthetics due to absence of naphthenes. However, the Shell/Pennzoil base oil is pure Fischer-Tropsch, where as far as I know, there are no longer any pure PAO’s on the market (all are blends of PAO and hydrocracked dino oil which because of the hydrocracked dino oil, have small amounts of naphthenes). That said, motor oil is a mix of base oil and additives, so since the disadvantage of the hydrocracked dino oil is very small, one can certainly not conclude that the Shell/Pennzoil lubes are best of the best. A better additive package could easily overcome the very small disadvantage of a few naphthenes coming from the hydrocracked dino oil in the others.
Last edited by LDB; Aug 13, 2023 at 08:16 AM.





About seal/gasket i have to say that every old "from tube paste seal" (more than 15 years in use) have been destroyed by ester based oils. No problem however with any after 2005 factory crafted gasket or recently applied pastes.
A genuine explanation of PAO versus Fischer-Tropsch is beyond the scope of this post, but one sentence descriptions follow. In the PAO route, you start with ethylene, polymerize that to make alpha olefins, use a different catalyst to polymerize the alpha olefins into PAO’s, then hydrotreat the PAO’s to make the finished long chain isoparaffins. In Fischer-Tropsch, you gasify natural gas into syngas (carbon monoxide plus hydrogen), then use the Fischer-Tropsch reaction to generate long chain paraffins which don’t have much chain branching, then isomerize the Fischer-Tropsch product into the finished long chain isoparaffins.
One could debate the small quality differences between PAO and Fischer-Tropsch isoparaffins, but both are clearly at least a bit better as lube base stocks than the hydrocracked dino oil synthetics due to absence of naphthenes. However, the Shell/Pennzoil base oil is pure Fischer-Tropsch, where as far as I know, there are no longer any pure PAO’s on the market (all are blends of PAO and hydrocracked dino oil which because of the hydrocracked dino oil, have small amounts of naphthenes). That said, motor oil is a mix of base oil and additives, so since the disadvantage of the hydrocracked dino oil is very small, one can certainly not conclude that the Shell/Pennzoil lubes are best of the best. A better additive package could easily overcome the very small disadvantage of a few naphthenes coming from the hydrocracked dino oil in the others.











Just stay with 5W30 or upgrade to 0W40 that newer vettes have gone to as factory fill.




