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Nice headline/subject...before I opened I thought this post is going to go in a very different direction!
For me it 100% depends on what I am shooting and how long outside. I rarely shoot in the 10-4pm window outside as the sun is too high in the sky so on a "normal" shoot I usually wear a baseball cap no sunglasses. That said for shoots like last weekend (NHRA event) where I am outside for hours I wear a hat very similar to the one below which I can customize abit to give me a little more sun protection. In that case I also wear my Oakley Polarized Sunglasses...but only when I am not shooting.