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There is a ring seal around the piston. This seal is removed and the piston will pop out. If you have a sleeve, it should be shiny and have a fine finish to it. You can see that a sleeve has been installed by looking for the different metal color (the caliper is bored oversized and a sleeve pressed in)
I don't think that there is any easy way to tell if your calipers are sleeved untile you open them up. I've heard that there will be some kind of stamp or numbers on the caliper somewhere, but I've never seen them.
The pistons are very easy to remove. Once you have the two halves of the caliper separated, push the piston in all the way (watch out for squirting brake fluid) then use a flat screwdriver under the lip of the dust boot. Pops off with fairly little resistance. Once the boot is off, the piston will come right out.
Once the piston is out, it will be very easy to tell if you have sleeved calipers. If they are rusty and corroded, you don't. If they are nice and shiney, you do. Also, if you do have sleeved calipers, clean them out with a little rubbing alcohol on a paper towel. This removes any rubber residue (got that tip from VP&P).
The O-ring seal is just that, an O-ring looking seal. The lip seal is more rectangle and has a lip sealing surface. If you have lip seals and want to change over to O-ring, Order the kit from VBP( a supporting vendor) for the O-ring pistons and seals. It is an easy job and if you need any help thier techs can give you a hand.
I used the Oring kit from VBP - $125 or so.
It is a nice complete kit ... even antiseize on the new bolts.
All you'll need are the castings. I had some light scoring
on my stainless sleeves ... cleaned them up lightly with some
1000 grit wet/dry paper. They are installed, bled, and currently
no leaks.