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Corvetter's greetings! Just found this forum and got lots of questions for you smart folks. I'll attack only one at a time. I have an 89 Coupe, six speed that will not start when the temp goes below aproximately 45 degrees. Turns over great but not a single hit. Shoot starting fluid through the throttle body and it starts right up, and will start great till it sits for 8 hours or so and cold soaks. I was told the coolant sensor was bad, replaced it and no difference. (How I long for a manual choke!)
It's time to break out the FSM and start following the trouble shooting charts. The three most common causes are fuel pressure bleeding off, a defective ECT sensor, and a bad fuel pressure relay. All these causes can be diagnosed and components tested before you start buying parts.
Definitely check the fuel pressure. I had a similar problem, wouldn't start cold on the first try (usually would catch on the third). If you hook a fuel pressure gage to the fuel rail and turn the car on (don't crank it), the fuel pump will cut on for 2 seconds and the pressure should go up to about 45ish psi. If it starts to bleed off rather quickly (mine bled to 0 psi in about 5 seconds) after that 2 seconds is up, then you have a leak somewhere. Mine was an injector.
There is a great flow chart on page 6E3-A-19 of the service manual that describes the fuel system diagnosis, but of course, I'd be sure to test everything (not just fuel). Parts get expensive quick.