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To compensate for your high compression you can use very high octance.
Theoretically, 14.7 psi will double your hp. Then you need to take into account losses due to supercharger pulley losses and increase in temperature of air coming out of the blower.
I wouldn't think that you could run more than 5-6psi with out having some major issues, for a good supercharged engine you would want 8 or 9:1 compression. Unless of course you want to start running some type of ethenol or methenol.
I'm guessing that you have a large overlap cam in the car as well. These kind of cams aren't the norm for a forced induction setup.
It would be easier and a lot less work just to spray a 100 shot on top of what you have instead of going through the trouble and cost of setting up a supercharger and all the tuning for a similar gain.
15 psi on alcohol would be right up your alley! E85 likes compression very similar to Methanol and it runs nice and cool.. if you have E85 at a pump near you then you are all set, I'd say let her rip. figure at 15psi with a properly sized compressor unit you can count on a solid gain of ~85%+ of your current power level. I know you rock a solid axle out back but I imagine you'll find the next weakest links!