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Check to make sure your throttle is opening all the way. Have someone press the pedal to the floor while you look in the throttle body. It is probably a matter of adjusting throttle linkage so it opens all the way.
If you've checked visually and the throttle blades are in fact in the WOT position--then remove the connector at the TPS-- jumper the grey and the blue wire together--turn key on--scan tool should show 4.5 to 5.0 volts--if you have this reading--then TPS is faulty.
Check the throttle linkage comming from the ASR. There is an adjustment button on it. It's fairly common for older C4's to need some adjustment. Sometimes mine would read less then 100% in TTS also. I could always tell it needed to be adjusted becuase I would lose major pickup at WOT and my trans would not downshift. I think my cable may need replacement however they dont make these anymore and I havent been able to find a correct replacement. I havent had any trouble with it in a long time though and I just did a couple of data logs the other day.
Either Datamaster is no reading it correctly or the TPS could be bad,or it is not open 100%. If you have never measured this before and have no base line for this measurement, then I would measure it manually with a DVM.
I use a long pin that goes up alongside the wire to make contact for the measurement You can also use a strait pin and puncture the wire. What you're looking for is to make sure one end is at ground potential measuring 0.00 volts. The high side should measure 5.0 volts (from the PCM), and then you can read the wiper voltage directly as you open and close the throttle.
Just for FYI, I measured mine using a Tech1 and got 0.64 closed and 4.14 volts at 100% open. Yours may be slightly different. I did measure the voltage with a meter but it's been so long I don’t remember what the exact voltages was.
I got the same voltage at 85% that you did. Maybe the throttle is not open all the way.
Check the throttle linkage comming from the ASR. There is an adjustment button on it. It's fairly common for older C4's to need some adjustment. Sometimes mine would read less then 100% in TTS also. I could always tell it needed to be adjusted becuase I would lose major pickup at WOT and my trans would not downshift. I think my cable may need replacement however they dont make these anymore and I havent been able to find a correct replacement. I havent had any trouble with it in a long time though and I just did a couple of data logs the other day.