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I finally fixed my code 32 problem, after some great advice from you guys I put yet another temp switch in and this seems to have sorted the problem.
As for the hard start when hot, since I got rid of the 32, if I just 'tap' the gas as it starts, all is well and I have had no problems.
Tested it this weekend with a longish journey (250 miles) in hot weather (29 C) with a few bad jams etc and I stopped the car a few times and it started fine.
I am not sure what the correct procedure is for a hot restart but if I just fire it up and don't touch the gas, it stalls after about 90 seconds