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Any competent alignment shop should be able to do the job. The biggest difference is in the camber setting, both front and rear. According to GM document #776629 the camber for FE1 & FE3 suspension is anywhere between +1.3 degree to -.7 degree, with -.2 being the center. For the FE4 (Z06) suspension, the setting is between -.2 degree to-1.2 degree with -.7 being the center. If you have the camber set anywhere within these ranges, then you'll be within GM specs.
I had mine aligned to Z06 specs 0.75 negative camber all around. With non-runflats you should not see any unusual tire wear. Actually probably better life compared to the stock alignment. Runflats are so stiff that they would wear funny.
Old topic here but a good one.
I suggest you align your car to your specs. The toe settings are the same on your car and the Z06 anyway and the caster is close.
Do not tell the tech to align your car to Z06 specs. He might just align it to within tolerances for the specs and you may get the same alignment as you have right now.
Someone else posted to this thread that he had Z06 specs but he only has .75 degrees of negative camber. Nothing wrong with that but the Z06 alignment can go to 1.2 degrees of negative camber and still be within specs.
His car is still within specs for a non Z06 car.
Tell the tech that you want all corners to have 1 degree of negative camber or whatever camber you want. Then set the toe and caster in specs for your car.
Make sure you get and keep the before and after alignment sheets.
Remember that the corvettes like more negative camber for cornering but the tradeoffs when going out of specs on camber are increased tire wear and premature wear of the suspension parts.
Dave