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Stainless...most expensive and most durable. Stainless does not rust.
Chrome...not as expensive as Stainless, but the tubes will rust.
Ceramic...least expensive of the three and first to rust.
I do not recommend stainless steel if you want that nice silver-gray color a year or two from now. Stainless steel headers to not stay stainless.
I am in the process of replacing my stainless steel headers with ceramic coated headers. The stainless steel develops a mottled golden brown color that darkens over time. The same happened on our son's car but not as dark.
Stainless steel headers are also very hot. I fried three sets of spark plug wires in just a couple thousand miles of normal driving. I doubt chrome headers would be any cooler.