I confess that I haven't looked into how the chime works. But, the likelihood that there is a "chime wire" is exceedingly slim. The C5 has a multiplexed architecture. What does this mean? It means that instead of individual wires for every conceivable signal, there is instead a communications bus, much like the Ethernet computer network that links the PCs in your home, work, or school. All of the control units that need to exchange data can communicate and exchange data over this bus. For example, the instrument cluster needs to know the road speed, but there is no "road speed signal wire" from the ABS ECU to the instrument cluster. Instead, the ABS ECU broadcasts the road speed data over the communication bus and the instrument cluster monitors the bus and drives the speedometer display accordingly. Similarly, the radio also monitors the road speed data from the ABS ECU, so that it can automatically increase the volume, in order to compensate for road noise at high speeds.
Without performing any research, my first impression would be that the logic for when the chime needs to be enabled is probably located in the body control module and when the specified conditions are met, the body control module likely sends a message to the instrument cluster requesting it to enable the chime. Once again, this is only a guess. There may be some clues in the workshop manual, or the electrical diagram, but as a rule, this sort of data is not generally provided to the dealer techs, unless they have a specific problem and they contact the manufacturer about it, directly.
Per
@bookyoh 's suggestion, you might search through the archives of this site to see if anyone has turned up any specifics on the chime function.