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Old Dec 3, 2008 | 09:08 AM
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Default Math question, thermal dynamics

So it was 28 degrees here this morning and I checked my tire pressure because the truck seemed alittle sloppy yesterday. I started thinking 'If I have a total of 28lbs@ 20deg F in the tire what will that pressure be this afternoon when it is 70 deg out?' assuming that the tire is the same temperature as teh air. I know there is a Calc formula or somthing but I am an electrical engineer and cant remember the thermal dynamics stuff. Anyone remember?
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Old Dec 3, 2008 | 09:13 AM
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PV=nRT

Ideal gas law.

The pressure is directly related to the temperature, but the temp is stated in absolute degrees, like Rankin.

PK
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Old Dec 3, 2008 | 09:15 AM
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Check out this link and if you figure it out let me know!

http://www.tremek.com/forum/technica...er-winter.html
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Old Dec 3, 2008 | 09:40 AM
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Use the ideal gas law as stated above but like this:

P* / T* = P / T

n, R, and V all cancel out because they are the same on both sides... Also, you can use F and lbs as long as it is the same on both sides.

P* and T* would be at the first temperature and pressure
P and T would be at the second temperature and pressure
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Old Dec 3, 2008 | 09:42 AM
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Originally Posted by DaJesterMan
Use the ideal gas law as stated above but like this:

P* / T* = P / T

n, R, and V all cancel out because they are the same on both sides... Also, you can use F and lbs as long as it is the same on both sides.

P* and T* would be at the first temperature and pressure
P and T would be at the second temperature and pressure
No, you can't use degrees farenheit. Must be degrees Rankin. You also want to use absolute pressures, not gauge pressures.
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Old Dec 3, 2008 | 09:46 AM
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Originally Posted by RetiredMarine20
Check out this link and if you figure it out let me know!

http://www.tremek.com/forum/technica...er-winter.html
This is a good start, but they get a bunch of stuff wrong. First, as stated above, if you want to use the ideal gas law, you must use absolute temperatures and pressures. They use absolute temperatures (but mix units for an unexplained reason, that is OK though), but use gauge pressures so their calculations are not correct.

Secondly, if I am controlling for temperature on a race course, I want to adjust the pressure at operating temperature, not cold temperature. If we make the assumption that the tire will reach the same operating temperature regardless of the ambient temperature, then they are OK (except for the aforementioned use of gauge pressure), but I am not sure I would be comfortable with their methodology if I was going to be screaming around a concrete ringed oval at 200+ mph, but that is just me.
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Old Dec 3, 2008 | 10:14 AM
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Awesome, thanks I will get out the calculator and start poking around.
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Old Dec 3, 2008 | 11:15 AM
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You are incorrect about the units... the reason for using absolute temperature (Kelvin or K) and other metric units of measurement is because the constant R uses these units. Since R is canceled from both sides, there is no need to use these units... Calculate the units for youself, they work out. Using F and psi on one side and F on the other side will give you psi for the unknown. This will give you a rough estimate because real gases are not ideal... but what are we, chemistry professors?
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Old Dec 3, 2008 | 11:27 AM
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I was once told by my Michelin rep that the real world relationship is roughly 1psi per 10 degrees temperature change. So 28 psi at 28 degrees would read about 32 psi at 70 degrees. (remember, always check pressures cold, ie. before driving car). Don't know how accurate, but seems about right...
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Old Dec 3, 2008 | 11:33 AM
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You can always spend $30 and get nitrogen put into your tires... Nitrogen expands less than oxygen. Of course, AIR is 80% nitrogen to begin with.... {that 'nitrogen in tires' thing is a great deal if you can find a "patsy" to fall for it}
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Old Dec 3, 2008 | 11:58 AM
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Originally Posted by DaJesterMan
You are incorrect about the units... the reason for using absolute temperature (Kelvin or K) and other metric units of measurement is because the constant R uses these units. Since R is canceled from both sides, there is no need to use these units... Calculate the units for youself, they work out. Using F and psi on one side and F on the other side will give you psi for the unknown. This will give you a rough estimate because real gases are not ideal... but what are we, chemistry professors?
You can get the ideal gas law constant stated in any units you want. For a simple calculation like this, you can mix units like PSI and degrees kelvin for exactly the reason you mentioned, everything else gets canceled out.

Am I a Chemistry Professor? No. Chemical Engineer?
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Old Dec 3, 2008 | 12:00 PM
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Originally Posted by 7T1vette
You can always spend $30 and get nitrogen put into your tires... Nitrogen expands less than oxygen. Of course, AIR is 80% nitrogen to begin with.... {that 'nitrogen in tires' thing is a great deal if you can find a "patsy" to fall for it}

People who put Nitrogen in their tires are suckers. Do the smart thing like I did, fill up with HELIUM!!! You won't believe the performance improvement!
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Old Dec 3, 2008 | 12:12 PM
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Hey I am just a dumb old Grunt so I know when it is cold, air up the tires!!
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Old Dec 3, 2008 | 12:31 PM
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I have a chart from Goodyear and the psi change is about 1lb for every 5 degrees. This is what I use as a basis for fleet pressures every spring and fall.
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Old Dec 3, 2008 | 12:51 PM
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What's wrong with waiting until it's 70* outside and checking the tire pressure?
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Old Dec 3, 2008 | 12:57 PM
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Originally Posted by PKguitar
People who put Nitrogen in their tires are suckers. Do the smart thing like I did, fill up with HELIUM!!! You won't believe the performance improvement!
Helium ???? wouldnt that reduce traction?sorta like the car in Flubber?
But on the serious side I'm going to bookmark this thread in case i run into a need for one of you to work a formula for me.
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Old Dec 3, 2008 | 12:59 PM
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Originally Posted by 74Blackfoot
What's wrong with waiting until it's 70* outside and checking the tire pressure?
That'd be too simple, Peace,,,Moosie
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Old Dec 3, 2008 | 01:03 PM
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Originally Posted by PKguitar
People who put Nitrogen in their tires are suckers. Do the smart thing like I did, fill up with HELIUM!!! You won't believe the performance improvement!


Reduces unsprung weight.
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Old Dec 3, 2008 | 01:07 PM
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Originally Posted by 7T1vette
Nitrogen expands less than oxygen.
No, as was stated, PV=nRT. The Pressure times the Volume is equal to the Number of moles times the gas constant (R) times the Temperature.

Avogardo's number (6.02x10^23) is the number of atoms that is equal to the atomic weight in grams and is defined as one mole.

Avogadro's Law states "Equal volumes of gasses, measured under the same conditions of temperature and pressure, contain equal numbers of molecules."

The type of gas has no bearing on the equation.

Last edited by toddalin; Dec 3, 2008 at 01:19 PM.
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Old Dec 3, 2008 | 01:45 PM
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Originally Posted by DWncchs
Helium ???? wouldnt that reduce traction?sorta like the car in Flubber?
But on the serious side I'm going to bookmark this thread in case i run into a need for one of you to work a formula for me.
It does reduce traction due to the reduction of the weight of the car, but that is way more than offset by the reduction of spinning weight in the wheels due to the lighter gas in the tires.
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