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There are a LOT of things that will cause belt noise. I really doubt the heat under hood has anything to do with it. Have you checked belt alignment? Pulley wear? The best belt for noise control is Bando.
The harmonic balancer on the crankshaft can be the source of belt squeaking, if the harmonic balancer rubber bushings move out of place. I've had this happen twice; once on a 2000 C5 and again on a 2006 C6. You can quickly spot this problem by watching the harmonic balancer while the engine is idling. If you see ANY wobble, replace the balancer.